Analytical Techniques: Atomic Absorption Spectrometry

Darryl D. Siemer, Westinghouse Idaho Nuclear Company

General Use

- Quantitative analyses of approximately 70 elements

Examples of Applications

- Trace impurities in alloys and process reagents

- Water analysis

- Direct air sampling/analysis

- Direct solids analysis of ores and finished metals

Samples

- Form: Solids, solutions, and gaseous (mercury)

- Size: Depends on technique used - from a milligram (solids by graphite furnace atomic absorption spectrometry) to 10 mL of solution for conventional flame work

- Preparation: Depends on the type of atomizer used; usually a solution must be prepared

Limitations

- Detection limits range from subparts per billion to parts per million

- Cannot analyze directly for noble gases, halogens, sulfur, carbon, or nitrogen

- Poorer sensitivity for refractory oxide or carbide-forming elements than plasma atomic emission spectrometry

- Basically a single-element technique

Estimated Analysis Time

- Highly variable, depending on the type of atomizer and technique used

- Sample dissolution may take 4-8 h or as little as 5 min

- Typical analysis times range from approximately 1 min (flames) to several minutes (furnaces)

Capabilities of Related Techniques

- Inductively coupled plasma atomic emission spectrometry and direct current plasma atomic emission spectrometry are simultaneous multielement techniques with a wider dynamic analytical range and sensitivities complementing those of atomic absorption spectrometry. They cost considerably more to set up and require more expert attention to potential matrix interference (spectral) problems


Reprinted with permission of ASM International®.

 

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