Analytical Services: Inductively Coupled Plasma Atomic Emmission Spectroscopy
Lynda M. Faires, Analytical Chemistry Group, Los Alamos National Laboratory
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General Use |
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- Simultaneous multielement analysis |
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- Quantitative and qualitative analysis for over 70 elements
with detection limits in the parts per billion (ng/mL) to
parts per million ( |
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- Determination of major, minor, and trace elemental components |
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Examples of Applications |
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- Composition of metal alloys |
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- Trace impurities in alloys, metals, reagents, and solvents |
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- Analysis of geological, environmental, and biological materials |
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- Water analysis |
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- Process control |
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Samples |
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- Form: Liquids, gases, and solids; liquids are most common |
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- Size: 5 to 50 mL of solution, 10 to 500 mg of solids |
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- Preparation: Most samples are analyzed as solutions; solutions can be analyzed as received, diluted, or preconcentrated as required; solids must usually be dissolved to form solutions; gases may be analyzed directly |
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Limitations |
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- Detection limits parts per billion to parts per million |
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- Cannot analyze for noble gases |
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- Halogens and some nonmetals require vacuum spectrometer and optics |
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- Sensitivity poor for alkali elements, especially rubidium; cannot determine cesium |
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Estimated Analysis Time |
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- Dissolution of solids in sample preparation may require up to 16 h |
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- Analysis may require minutes to several hours |
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Capabilities of Related Techniques |
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- Direct-current arc emission spectrography: Samples may be analyzed directly as solids; sensitivity and quantitative precision poorer; longer analysis time required |
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- Atomic absorption spectroscopy: Single-element analysis; better sensitivity for most elements, especially by using electrothermal atomization, but not as good for refractory elements; more limited dynamic range |
Reprinted with permission of ASM International®.
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